The rate of nuclear fusion in the molecule is of the order of 1012 s-1, hence it is too fast to measure experimentally. The reaction is strongly dominated by the resonance 5He , which lies about 55 keV above threshold. Because of the centrifugal barrier of the J=1 states of the molecule, fusion is expected to take place mainly from J=0 states, i.e., (J,v)=(0,1) and (0,0), into which the initial state (1,1) is quickly converted via fast E1Auger transitions.
For , on the other hand, the transition from is strongly suppressed (since it requires spin flip, analogous to the ortho-para transitions in the homonuclear hydrogen molecule), and fusion takes place mainly from the J=1 states, if the molecule is resonantly formed in the (1,1) state. This in fact offers a unique opportunity to study the p wave fusion reaction at very low energy, which is difficult to do in a beam experiment. An interesting feature of this reaction is that the fusion width ratio of the (n+ 3He) channel to the (p + t) channel is about 1.4, apparently violating charge symmetry.
In a simple approach, the fusion rate is calculated by treating three-body
Coulomb physics (molecular wave functions) and nuclear physics
separately [54], a method known as factorization. For ,
we have
More accurate approaches treat the nuclear force dynamically by directly incorporating it as a complex potential in the three-body Hamiltonian (optical potential method) [55,56], or as complex boundary conditions at the nuclear surface (R-matrix method) [57,58,59]. These elaborate approaches agree rather well with each other, as well as with the simple factorization approach.
In collisions, fusion ``in flight'', i.e., without forming a bound molecule, is also possible, and its rates have been calculated by various methods including, most recently, Faddeev equations (see [26] and references therein). The reactions are enhanced, compared to bare nuclear collisions, especially if virtual states exist, due to the increased overlap of the nuclear wave functions.