Relaxation in ro-vibrational states of MMC would change the Q-value
available for the back decay reaction, affecting the energy. According to the estimate of Lane [151], vibrational
de-excitation rates appear to be a few orders of magnitude smaller than the
MMC decay rate (although the former increases with the target temperature),
hence we ignore its contribution here. Future calculations of the MMC
vibrational relaxation would be very helpful.
Rotational transitions in the MMC have been calculated by Ostrovskii and
Ustimov [153], and by Padial et al. [154] for the
case of targets in thermal equilibrium. Ostrovskii and Ustimov estimate
relaxation rates of order of 1013 s-1, while Padial et al.,
who claim higher accuracy, give
s-1 at 300
K. Given the MMC decay rate of
s-1, if rotational
thermalization is achieved only partially, then detailed rate
equations
should be solved to calculate the energy distribution of back-decayed
.
In our calculation below, we give the two extreme cases of complete
rotational thermalization and no thermalization at all.